FLAC is the audiophile's handshake: CD-perfect sound at roughly half the shelf space. It was born in 2001, Josh Coalson; now kept by the open Xiph.Org Foundation, and its real weak spot is fitting in pockets: lossless is still large: and charming Apple's own apps.
WMV is a time capsule from the Windows XP years: tidy little files with dated manners. Windows Media Video, usually inside an ASF container; once the backbone of DRM movie rentals. That makes it the right destination when what you need is old Windows archives and PowerPoint decks that still insist on it.