MOV is Apple's homebody: gorgeous on a Mac, awkward everywhere else. It was born in 1991, Apple's QuickTime team, and its real weak spot is traveling: Windows, Android and the web would all rather meet an MP4.
WMV is a time capsule from the Windows XP years: tidy little files with dated manners. Windows Media Video, usually inside an ASF container; once the backbone of DRM movie rentals. That makes it the right destination when what you need is old Windows archives and PowerPoint decks that still insist on it.