WEBM is video the way browsers like it: open, royalty-free and built to stream. It was born in 2010, Google, out of its VP8 acquisition, and its real weak spot is life outside the browser: editors, TVs and Apple devices get picky.
WAV is audio with nothing taken away: every sample intact, every megabyte accounted for. Raw PCM samples in a RIFF wrapper. No compression of any kind. That makes it the right destination when what you need is recording, editing and mastering, where every last bit matters.