MOV is Apple's homebody: gorgeous on a Mac, awkward everywhere else. It was born in 1991, Apple's QuickTime team, and its real weak spot is traveling: Windows, Android and the web would all rather meet an MP4.
AVI is the veteran of desktop video: dependable in 1995, cranky about everything invented since. Audio Video Interleave: an early container that predates streaming and most codecs you'd use today. That makes it the right destination when what you need is opening old archives and humoring legacy Windows tools.